Thiamine hydrochloride (vitamin B1) as modifier agent for TiO2 nanoparticles and the optical, mechanical, and thermal properties of poly(vinyl chloride) composite films

Abstract

In the present investigation, TiO₂ nanoparticles (NPs) were used for improving the thermal, mechanical and optical properties of poly(vinyl chloride) (PVC) matrix. To prevent the aggregation of TiO₂ NPs, surface modification of TiO₂ NPs was performed using vitamin B₁ as a natural organic molecule with environmentally friendly and inexpensive properties. PVC nanocomposite (NC) films were prepared with different contents of TiO₂ NPs via ultrasonic irradiation as a fast method and then the NCs were investigated using various techniques. Transmission electron microscopy images of NC films showed that TiO₂ NPs were uniformly placed into the polymer matrix. Thermogravimetric analysis results showed enhancement in thermal stability of all NCs. From mechanical tests it was found that increasing the elongation at break and reducing the Young's modulus lead to increasing toughness of NC films. Water contact angle results indicated that the hydrophobicity of NCs were enhanced with increasing the concentration of TiO₂ NPs.