Synthesis of Novel Monomers Via Benzyne and Bisbenzyne Intermediates

ABSTRACT

2 - Oxo - 1,3 - bis (methoxy carbonyl) - 2 - H - cyclopenta [i]

acenaphthylene is prepared from base - catalyzed condensation of dimethyl

- 1,3 - acetone dicarboxylate with acenaphthenequlnone . Benzyne generated

from anthranilic acid is trapped with this cyclone and 7,12 - dimethyl

carboxylate benzo [k] fluoranthene as a new monomer is obtained In

quantitative yield, Bisbenzyne from aprofic diazotization of 3,3' - dicarboxy -

4,4' - diaminobiphenyl is also trapped with this cyclone and leads to the

formation of tetra functional methyl carboxylate of bisbenzo [k] fluoranthene

derivative.

https://people.iut.ac.ir/en/mallakpour/content/synthesis-novel-monomers-benzyne-and-bisbenzyne-intermediates-0